Ternary nanocomposites of low density, high density and linear low density polyethylenes with the compatibilizers E-MA-GMA and E-BA-MAH

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Tezin Türü: Doktora

Tezin Yürütüldüğü Kurum: Orta Doğu Teknik Üniversitesi, Fen Bilimleri Enstitüsü, Fen Bilimleri Enstitüsü, Türkiye

Tezin Onay Tarihi: 2011

Öğrenci: FATMA IŞIK COŞKUNSES

Danışman: ÜLKÜ YILMAZER

Açık Arşiv Koleksiyonu: AVESİS Açık Erişim Koleksiyonu

Özet:

The effects of polyethylene, (PE), type, compatibilizer type and organoclay type on the morphology, rheological, thermal, and mechanical properties of ternary low density polyethylene (LDPE), high density polyethylene (HDPE), and linear low density polyethylene (LLDPE), matrix nanocomposites were investigated in this study. Ethylene – Methyl acrylate – Glycidyl methacrylate terpolymer (E-MAGMA) and Ethylene – Butyl acrylate- Maleic anhydrate terpolymer (E-BA-MAH) were used as the compatibilizers. The organoclays selected for the study were Cloisite 30B and Nanofil 8. Nanocomposites were prepared by means of melt blending via co-rotating twin screw extrusion process. Extruded samples were injection molded to be used for material characterization tests. Optimum amounts of ingredients of ternary nanocomposites were determined based on to the mechanical test results of binary blends of PE/Compatibilizer and binary nanocomposites of PE/Organoclay. Based on the tensile test results, the optimum contents of compatibilizer and organoclay were determined as 5 wt % and 2 wt %, respectively. XRD and TEM analysis results indicated that intercalated and partially exfoliated structures were obtained in the ternary nanocomposites. In these nanocomposites E-MA-GMA compatibilizer produced higher d-spacing in comparison to E-BA-MAH, owing to its higher reactivity. HDPE exhibited the highest basal spacing among all the nanocomposite types with E-MA-GMA/30B system. Considering the polymer type, better dispersion was achieved in the order of LDPE