Akademik Veri Yönetim Sistemi
Tezin Türü: Yüksek Lisans
Tezin Yürütüldüğü Kurum: Orta Doğu Teknik Üniversitesi, Mühendislik Fakültesi, İnşaat Mühendisliği Bölümü, Türkiye
Tezin Onay Tarihi: 2013
Öğrenci: EMRE TATLI
Danışman: MUSTAFA TOKYAY
Özet:This thesis work aims the ionic liquid pretreatment of peanut shells for co-production of glucose as fermentable sugar and lignin, considering a multi product perspective. The effects of ionic liquid type and pretreatment time period on the sugar and lignin yields were investigated, as the particle size and temperature parameters were determined in the preliminary studies. Peanut shells were pretreated at constant temperature, 150 oC, for 5, 15 and 30 minutes with 1-ethyl-3-methylimidazolium acetate and for 15, 30 and 60 minutes with 1-ethyl-3-methylimidazolium chloride. The pretreated peanut shells were then subjected to enzymatic hydrolysis in order to produce fermentable sugars, mostly, glucose. The solid residue obtained upon enzymatic hydrolysis was analyzed in terms of lignin quantity. 1-ethyl-3-methylimidazolium acetate pretreatment for 15 minutes resulted in the maximum reducing sugar and lignin yields; 28 g of reducing sugar and 20 g of solid residue with 70% lignin were obtained per 100 g of peanut shells. Higher pretreatment time resulted in lower yields. Moreover, no optimal time period for 1-ethyl-3- methylimidazolium chloride pretreatment was obtained, since reducing sugar and lignin yields increased as the time period increased. Also all reducing sugar and lignin yields were lower than that obtained with 1-ethyl-3-methylimidazolium acetate. Lignin obtained upon enzymatic hydrolysis of 1-ethyl-3-methylimidazolium acetate pretreated peanut shells were characterized by SEM, FTIR, TGA and XRD analyses, which also showed the morphological and structural effects of pretreatment and enzymatic hydrolysis on peanut shells; and used as concrete admixture, which increased the flow of the concrete by 6%.