Triclosan removal by nanofiltration from surface water

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Tezin Türü: Yüksek Lisans

Tezin Yürütüldüğü Kurum: Orta Doğu Teknik Üniversitesi, Mühendislik Fakültesi, Çevre Mühendisliği Bölümü, Türkiye

Tezin Onay Tarihi: 2013

Tezin Dili: İngilizce

Öğrenci: ABDULLAH ÖGÜTVERİCİ

Asıl Danışman (Eş Danışmanlı Tezler İçin): Ülkü Yetiş

Eş Danışman: Filiz Bengü Dilek

Özet:

Nowadays, organic pollutants occurring in surface waters have raised substantial concern in public. Triclosan (TCS) is one of the antimicrobial agents which are utilized in both domestic and industrial application. In this study nanofiltration (NF) of TCS in surface water was investigated. Laboratory scale cross-flow device is operated in total recycle mode and DK-NF and DL-NF membranes were used. Kesikköprü Reservoir (Ankara) water was used as raw water. Effect of natural organic matter (NOM) content of raw water on TCS removal is searched through addition of humic acid (HA) into the raw water as to represent for NOM. Steady state permeate fluxes are monitored throughout the experiments to explore the flux behavior of the membranes. During the experiments, performance of the membranes is assessed by monitoring TCS, as well as other water quality parameters, such as UVA254 and total organic carbon (TOC) in the feed and permeates waters. Results obtained put forward that TCS removal by NF membrane is not as same as reported in the literature. In the literature, membrane removal efficiency is reported as above 90%. However, this study proved that this would be true if and only if one does not considers the adsorption of TCS by the system itself, in the absence of membrane. It is now clear that, because of adsorption of the TCS onto the experimental set up (feed tank, pipings etc.); the real TCS removal efficiency of the nanofiltration is around 60-70%.