Syntheses, electrochemical and photophysical properties of biphenyl containing conjugated copolymers

DENIZ T. K., NURIOGLU A. G., UNLU N. A., SENDUR M., TOPPARE L., ÇIRPAN A.

POLYMER, cilt.54, sa.9, ss.2243-2249, 2013 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 54 Sayı: 9
  • Basım Tarihi: 2013
  • Doi Numarası: 10.1016/j.polymer.2013.02.052
  • Dergi Adı: POLYMER
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.2243-2249
  • Anahtar Kelimeler: Conjugated polymers, Electrochromism, Donor-acceptor theory, OPTICAL-PROPERTIES, LARGE-AREA, BAND-GAP, MEH-PPV, ELECTROLUMINESCENCE, AGGREGATION, POLYMERS, DONOR, PHOTOLUMINESCENCE, BENZOTHIADIAZOLE
  • Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

Poly 4-(biphenyl-4-yl)-4'-tert butylspiro[benzo[d]imidazole-2,1'-cyclohexane] (P1), Poly 4-(biphenyl-4-yl)2-dodecyl-2H-benzo[d][1,2,3]triazole (P2), Poly(4-(5-(biphenyl-4-yl)-4-hexylthiophen-2-yl)-2-dodecyl-7(4-hexylthiophen-2-yl)-2H-benzo[d][1,2,3]triazole (P3) were synthesized via Suzuki cross coupling polycondensation reaction. Polymers are thermally stable with decomposition temperatures above 300 C. Electrochemical and optical studies revealed that P2 and P3 exhibit reversible redox behavior with multichromic properties. Polymers showed highly fluorescent properties both in thin film and solution forms. Photoluminescence quantum efficiencies of P2 and P3 are 0.70 and 0.57 in chloroform respectively. (C) 2013 Elsevier Ltd. All rights reserved.