Role of copper species in the oxidative dimerization of arylboronic acids: Synthesis of symmetrical biaryls

Demir A., Reis O., Emrullahoglu M.

JOURNAL OF ORGANIC CHEMISTRY, cilt.68, sa.26, ss.10130-10134, 2003 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 68 Sayı: 26
  • Basım Tarihi: 2003
  • Doi Numarası: 10.1021/jo034680a
  • Dergi Adı: JOURNAL OF ORGANIC CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.10130-10134
  • Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

Certain Cu(I) and Cu(II) salts are able to mediate the dimerization of arylboronic acids in DMF. They provide the corresponding symmetrical biaryls in moderate to very good yields. It is possible to run the reaction catalytically under an oxygen atmosphere without a significant loss of yields.