DERIVATIVES OF POLY(PYRROLE) WITH DECONJUGATED CARBONYL SUBSTITUENTS IN BETA-POSITION

VOIGT, M; GEISSLER, U; HAASE, V; VOIGT, B; HALLENSLEBEN, ML; TOPPARE, LEVENT

doi:10.1016/0379-6779(93)90265-x

DERIVATIVES OF POLY(PYRROLE) WITH DECONJUGATED CARBONYL SUBSTITUENTS IN BETA-POSITION

VOIGT M., GEISSLER U., HAASE V., VOIGT B., HALLENSLEBEN M., TOPPARE L.

SYNTHETIC METALS, cilt.55, ss.1441-1446, 1993 (SCI-Expanded, Scopus)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 55
Basım Tarihi: 1993
Doi Numarası: 10.1016/0379-6779(93)90265-x
Dergi Adı: SYNTHETIC METALS
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.1441-1446
Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

Four omega-(3-pyrrolyl)esters were investigated by cyclic voltammetry, electron microscopy and conductivity measurements. The corresponding poly(pyrrole) derivatives exhibit enhanced conductivities compared to poly(3-acylpyrrole)s, and their electrochemical behavior resembles that of poly(3-alkylpyrrole)s rather than the poly(3-acylpyrrole) derivatives. Ester saponification occurring during electropolymerization was examined by gas chromatography.