DERIVATIVES OF POLY(PYRROLE) WITH DECONJUGATED CARBONYL SUBSTITUENTS IN BETA-POSITION


VOIGT M., GEISSLER U., HAASE V., VOIGT B., HALLENSLEBEN M., TOPPARE L.

SYNTHETIC METALS, cilt.55, ss.1441-1446, 1993 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 55
  • Basım Tarihi: 1993
  • Doi Numarası: 10.1016/0379-6779(93)90265-x
  • Dergi Adı: SYNTHETIC METALS
  • Sayfa Sayıları: ss.1441-1446

Özet

Four omega-(3-pyrrolyl)esters were investigated by cyclic voltammetry, electron microscopy and conductivity measurements. The corresponding poly(pyrrole) derivatives exhibit enhanced conductivities compared to poly(3-acylpyrrole)s, and their electrochemical behavior resembles that of poly(3-alkylpyrrole)s rather than the poly(3-acylpyrrole) derivatives. Ester saponification occurring during electropolymerization was examined by gas chromatography.