The facile synthesis of cyclopentanoid antibiotic kjellmanianone


Demir A. , Tanyeli C. , Gulbeyaz V., Akgul H.

TURKISH JOURNAL OF CHEMISTRY, vol.20, no.3, pp.244-248, 1996 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 20 Issue: 3
  • Publication Date: 1996
  • Title of Journal : TURKISH JOURNAL OF CHEMISTRY
  • Page Numbers: pp.244-248

Abstract

The synthesis of cyclopentanoid antibiotic Kjellmanianone is described in this study. The C-acylation of lithium enolates of 3-Methoxycyclopentenone by N-carbomethoxyimidazole or methylcyanoformate beta-ketoester, which when oxidized with Mn(III) acetate produces kjellmanianone in good yield.