The facile synthesis of cyclopentanoid antibiotic kjellmanianone

Demir A., Tanyeli C., Gulbeyaz V., Akgul H.

TURKISH JOURNAL OF CHEMISTRY, cilt.20, sa.3, ss.244-248, 1996 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 20 Sayı: 3
  • Basım Tarihi: 1996
  • Dergi Adı: TURKISH JOURNAL OF CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, TR DİZİN (ULAKBİM)
  • Sayfa Sayıları: ss.244-248
  • Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

The synthesis of cyclopentanoid antibiotic Kjellmanianone is described in this study. The C-acylation of lithium enolates of 3-Methoxycyclopentenone by N-carbomethoxyimidazole or methylcyanoformate beta-ketoester, which when oxidized with Mn(III) acetate produces kjellmanianone in good yield.