The facile synthesis of cyclopentanoid antibiotic kjellmanianone


Demir A. , Tanyeli C. , Gulbeyaz V., Akgul H.

TURKISH JOURNAL OF CHEMISTRY, cilt.20, ss.244-248, 1996 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 20 Konu: 3
  • Basım Tarihi: 1996
  • Dergi Adı: TURKISH JOURNAL OF CHEMISTRY
  • Sayfa Sayıları: ss.244-248

Özet

The synthesis of cyclopentanoid antibiotic Kjellmanianone is described in this study. The C-acylation of lithium enolates of 3-Methoxycyclopentenone by N-carbomethoxyimidazole or methylcyanoformate beta-ketoester, which when oxidized with Mn(III) acetate produces kjellmanianone in good yield.