Synthesis of a new system containing a pyramidalized double bond: Lack of reactivity of a strongly protected pyramidalized double bond


Saracoglu N., Balci M.

HELVETICA CHIMICA ACTA, cilt.84, ss.707-714, 2001 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 84 Konu: 3
  • Basım Tarihi: 2001
  • Dergi Adı: HELVETICA CHIMICA ACTA
  • Sayfa Sayıları: ss.707-714

Özet

The chemical reactivity of syn-3 was investigated. The experimental results showed that the central double bond of this system is inert toward chemical reactions. To determine the reactivity of this central double bond. we synthesized syn- and anti-7 and recorded their photoelectron spectra. Low first-ionization potentials of syn- and anti-7 (7.6 eV) dearly indicated that these compounds should be highly reactive.