Akademik Veri Yönetim Sistemi
ELECTROCHIMICA ACTA, cilt.536, 2025 (SCI-Expanded, Scopus)
High entropy oxide materials are new-generation materials with diverse possible applications in various fields, including electrocatalyst research. However, the effectiveness of non-stoichiometric high-entropy oxides remains unexplored. Using the well-established sol-gel method, this study synthesized five high-entropy oxides with varying deviations from stoichiometry. Variations in metal-oxygen bond lengths and work functions are observed by deviating from stoichiometric ratios without showing significant changes in oxygen vacancy content. Among the high-entropy oxides (HEOs), the Co-rich (Co0.3Fe0.175Cr0.175Mn0.175Zn0.175)(3)O-4 (Co-0.3) and (Co0.225Fe0.1Cr0.225Mn0.225Zn0.225)(3)O-4 (Fe-0.1) compositions demonstrate a better performance in OER, ORR, and battery applications attributed to their enhanced charge transfer rates and catalytic activity. Co-0.3 exhibited the lowest overpotential of 428 mV at a current density of 10 mA cm(-2) and the smallest Bifunctional Index (BI) of 0.95 V. Analysis reveals a non-linear correlation between Co and Fe content, work function, metal-oxygen bond length, and electrocatalytic activity. Our findings propose a better understanding of the effect of nonstoichiometry and Co and Fe synergy on high-entropy oxide for advancing electrocatalyst design.