INTRAZEOLITE METAL-CARBONYL KINETICS - (CO)-C-12 SUBSTITUTION IN MO(12CO)6-NA56Y BY PME3 AND (CO)-C-13

OZIN, GA; OZKAR, SAİM; PASTORE, HO; POE, AJ; VICHI, EJS

doi:10.1039/c39910000141

INTRAZEOLITE METAL-CARBONYL KINETICS - (CO)-C-12 SUBSTITUTION IN MO(12CO)6-NA56Y BY PME3 AND (CO)-C-13

Atıf İçin Kopyala

OZIN G., OZKAR S., PASTORE H., POE A., VICHI E.

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, sa.3, ss.141-143, 1991 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Basım Tarihi: 1991
Doi Numarası: 10.1039/c39910000141
Dergi Adı: JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED)
Sayfa Sayıları: ss.141-143
Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

The first kinetic study is reported for archetypical substitution reactions of PMe3 and 13CO with the well defined intrazeolite system, Mo(12CO)6-Na56Y, for which excellent isosbestic points and first order behaviour are obtained, the activation parameters indicate a highly ordered 'supramolecular' transition state consisting of activated Mo(12CO)6 and PMe3 or 13CO all anchored to the Na+ ions in the alpha-cage of the host lattice.