Pressure dependence of the Raman frequencies for the translational mode in ammonia solid II

Yurtseven, HASAN

doi:10.1016/j.jqsrt.2006.02.052

Pressure dependence of the Raman frequencies for the translational mode in ammonia solid II

Atıf İçin Kopyala

Yurtseven H.

JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER, cilt.102, sa.3, ss.409-417, 2006 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 102 Sayı: 3
Basım Tarihi: 2006
Doi Numarası: 10.1016/j.jqsrt.2006.02.052
Dergi Adı: JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.409-417
Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

We study here the translational mode of the ammonia solid II near the melting point by calculating its Raman frequencies as a function of pressure for the fixed temperatures of 230.4, 263.4 and 297.5 K. We perform this calculation of the Raman frequencies using the volume data by means of our Gruneisen relation. The Raman frequency shifts as the volume changes with the pressure, exhibit an anomalous behaviour near the melting point in the ammonia solid II.