SYNTHESIS-STUTTGART, no.10, pp.1655-1658, 2009 (SCI-Expanded)
Article / Article
Science Citation Index Expanded (SCI-EXPANDED), Scopus
phosphonocyanohydrins, diethyl cyanophosphonate, addition reactions, acyl phosphonates, nucleophilic additions, ACYL ANION EQUIVALENTS, CARBONYL-COMPOUNDS, BINOLAM-ALCL, PHOSPHORYLATION, REARRANGEMENT, PHOSPHONATES, CONVERSION, NITRILES, CATALYST, COMPLEX
Middle East Technical University Affiliated:
Cyanide ion catalyzed addition of acylphosphonates to diethyl cyanophosphonate furnished phosphonocyanohydrin O-phosphates in high yield. The reaction works via the phosphonate-phosphate rearrangement, followed by the addition of diethyl cyanophosphonate to the cyanohydrin phosphate anion.