Atıf İçin Kopyala
DEMİR A. G., Aybey A., Emrullahoglu M.
SYNTHESIS-STUTTGART, sa.10, ss.1655-1658, 2009 (SCI-Expanded)
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Yayın Türü:
Makale / Tam Makale
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Basım Tarihi:
2009
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Doi Numarası:
10.1055/s-0029-1216634
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Dergi Adı:
SYNTHESIS-STUTTGART
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Derginin Tarandığı İndeksler:
Science Citation Index Expanded (SCI-EXPANDED), Scopus
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Sayfa Sayıları:
ss.1655-1658
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Anahtar Kelimeler:
phosphonocyanohydrins, diethyl cyanophosphonate, addition reactions, acyl phosphonates, nucleophilic additions, ACYL ANION EQUIVALENTS, CARBONYL-COMPOUNDS, BINOLAM-ALCL, PHOSPHORYLATION, REARRANGEMENT, PHOSPHONATES, CONVERSION, NITRILES, CATALYST, COMPLEX
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Orta Doğu Teknik Üniversitesi Adresli:
Evet
Özet
Cyanide ion catalyzed addition of acylphosphonates to diethyl cyanophosphonate furnished phosphonocyanohydrin O-phosphates in high yield. The reaction works via the phosphonate-phosphate rearrangement, followed by the addition of diethyl cyanophosphonate to the cyanohydrin phosphate anion.