SOLID-STATE POLYMERIZATION OF BIS(TRICHLOROPHENOXO) COBALT(II) COMPLEX TO GIVE POLY(DICHLOROPHENYLENE OXIDE)


BASTURKMEN M., ISCI H., KISAKUREK D.

POLYMER INTERNATIONAL, cilt.30, ss.387-392, 1993 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 30 Konu: 3
  • Basım Tarihi: 1993
  • Doi Numarası: 10.1002/pi.4990300319
  • Dergi Adı: POLYMER INTERNATIONAL
  • Sayfa Sayıları: ss.387-392

Özet

Synthesis of four-coordinated (tetrahedral) trichlorophenol cobalt(II) complex with neutral ligand pyridine was achieved from the aqueous solution and its characterization was performed by UV-visible, IR spectral and CHN analysis. Solid state thermal polymerization of the complex was accomplished first at constant temperature employing different time intervals and secondly at constant decomposition time. The poly(dichlorophenylene oxide)s so synthesized were characterized by IR, H-1 NMR and C-13 NMR spectral analysis, T(g) determination, as well as measurement of molecular weight by a viscometric method.