Efficient one-pot synthesis of cyanoferrocene from ferrocenecarboxaldehyde using NH2OH center dot HCl/KI/ZnO/CH3CN system

KIVRAK A., Zora M.

JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol.692, no.11, pp.2346-2349, 2007 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 692 Issue: 11
  • Publication Date: 2007
  • Doi Number: 10.1016/j.jorganchem.2007.02.002
  • Journal Name: JOURNAL OF ORGANOMETALLIC CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.2346-2349
  • Keywords: nitriles, ferrocene, ferrocenyl, oximes, KI/ZnO, ferrocenecarboxaldehyde, ferrocenylcyanide, ferrocenyinitrile, ferrocenylcarbonitrile, cyanoferrocene, ONE-STEP CONVERSION, SOLVENT-FREE, BECKMANN REARRANGEMENT, HIGHLY EFFICIENT, NITRILES, ALDEHYDES, ALDOXIMES, DEHYDRATION, ANALOGS, CONVENIENT
  • Middle East Technical University Affiliated: Yes

Abstract

A new and efficient one-pot synthesis of cyanoferrocene from ferrocenecarboxaldehyde is described by employing the NH2OH center dot HCI/KI/ZnO/CH3CN system. (C) 2007 Elsevier B.V. All rights reserved.