Spectroscopic and crystal structure analysis of diamminebis(2,4,6-triiodophenolato-O) copper(II)
CRYSTAL RESEARCH AND TECHNOLOGY, cilt.41, sa.5, ss.523-527, 2006 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 41 Sayı: 5
- Basım Tarihi: 2006
- Doi Numarası: 10.1002/crat.200510616
- Dergi Adı: CRYSTAL RESEARCH AND TECHNOLOGY
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.523-527
- Anahtar Kelimeler: Cu(II) complex, triiodophenol, crystal structure, magnetic susceptibility, FTIR, DSC, STATE THERMAL-DECOMPOSITION, POLY(DIHALOPHENYLENE OXIDE)S, COMPLEXES, ETHYLENEDIAMINE, POLYMERIZATION, NICKEL(II)
- Orta Doğu Teknik Üniversitesi Adresli: Evet
Özet
The crystal structure of [Cu(C6H2I3O)(2)(NH3)(2)] (CCDC 238896) has been determined by x-ray diffraction. This monomeric centrosymmetric Cu(II) complex crystallizes in the monoclinic system. The CuO2N2 coordination sphere is trans-planar, [Cu-O: 1.943(5) angstrom and Cu-N: 1.972(7)] with the fifth and sixth coordination sites occupied by I atoms from the phenoxide ions [Cu-I-1: 3.3552(8) angstrom] to form a tetragonally elongated octahedral structure for CuO2N2I2 Coordination. The complex molecules hold together in a one dimensional chain true [100] direction by intermolecular hydrogen bonds. Differential scanning calorimeter, FTIR and magnetic susceptibility measurements were also performed in order to identify the title complex.