Redox Behavior of 2,3-Diamino-1,4-naphthoquinone and its <i>N</i>-Alkylated Derivatives
ELECTROANALYSIS, cilt.28, sa.11, ss.2855-2860, 2016 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 28 Sayı: 11
- Basım Tarihi: 2016
- Doi Numarası: 10.1002/elan.201600356
- Dergi Adı: ELECTROANALYSIS
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.2855-2860
- Açık Arşiv Koleksiyonu: AVESİS Açık Erişim Koleksiyonu
- Orta Doğu Teknik Üniversitesi Adresli: Hayır
Özet
Electrochemical reduction and oxidation potentials and standard heterogeneous electron transfer rate constants are reported for 2,3-diamino-1,4-naphthoquinone and two of its N-alkylated derivatives in acetonitrile. For two of the compounds, spectroelectrochemistry was used to obtain the absorption spectra of the radical cation and the radical anion. The compounds can be viewed as captodative biradicaloids and as such are of interest for photophysical studies of singlet fission.