ZnO-In2O3-SnO2 THIN FILM TRANSPARENT HEATERS: TUNABLE ELECTROTHERMAL PROPERTIES THROUGH SUBSTRATE TEMPERATURE AND POSTGROWTH ANNEALING


AKYILDIZ H., Can H. A., Kivrak B., ÖZTÜRK T.

KONYA JOURNAL OF ENGINEERING SCIENCES, vol.13, no.1, 2025 (ESCI) identifier identifier

Abstract

Amorphous thin films of ZnO-In2O3-SnO2 (a-ZITO) were manufactured using magnetron sputtering technique for the applications of thin film transparent heaters (TFTHs). For this purpose, a custom-made 3" sputtering target was prepared with a specific composition in terms of the atomic percentages (at.%) of Zn, In, and Sn cations. The impact of varying substrate temperatures on the characteristics of the samples investigated by depositing the films on glass substrates maintained at room temperature, 150 degrees C, and 250 degrees C. To improve the optical and electrical properties, post-growth annealing was carried out under forming gas atmosphere at 400 degrees C. Structural, morphological, optical, and electrical properties of the samples were thoroughly examined. Electrothermal characterization was performed on samples at room temperature and-40 degrees C to evaluate response time, saturation temperature, thermal homogeneity, stability, recyclability, thermal resistance, and the defogging/deicing capability of the produced TFTHs. The films produced at 150 degrees C demonstrated an exceptional electrothermal response, with the thermal resistance calculated to be 181.7 degrees Ccm2/W under 12 V input. With a measured power density of 0.4635 Watt/cm2, this heater was able to melt all ice and evaporate water droplets on the surface within 173 s, indicating a promising performance for commercial defogging/deicing applications.