A ferrocene functionalized multichromic p and n dopable donor-acceptor-donor type conjugated polymer

Ozdemir S., BALAN A., BARAN D., DOĞAN Ö., Toppare L.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, cilt.648, sa.2, ss.184-189, 2010 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 648 Sayı: 2
  • Basım Tarihi: 2010
  • Doi Numarası: 10.1016/j.jelechem.2010.07.010
  • Dergi Adı: JOURNAL OF ELECTROANALYTICAL CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.184-189
  • Anahtar Kelimeler: Ferrocene, Multichromism, Donor-acceptor-donor, Conjugated polymer, PROCESSABLE GREEN, ELECTROCHROMIC POLYMERS, BAND-GAP, REDOX, ELECTROPOLYMERIZATION, FILM, CONTRAST, SENSOR, STATE
  • Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

Ferrocene substituted donor-acceptor-donor type polymer; poly(5,8-bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-2-(naphthalen-2-yl)-3-ferrocenyl-4a,8a-dihydroquinoxaline) (PDEFNQ) was synthesized and its electrochromic properties were investigated. Cyclic voltammetry and spectroelectrochemistry studies for PDEFNQ showed that it is a multichromic green to transmissive polymer with high tendency to be both p and n doped. PDEFNQ is foreseen as a promising candidate for various applications. (C) 2010 Elsevier B.V. All rights reserved.