Ceria supported ruthenium(0) nanoparticles: Highly efficient catalysts in oxygen evolution reaction


DEMİR ARABACI E. , AKBAYRAK S., ÖNAL A. M. , ÖZKAR S.

JOURNAL OF COLLOID AND INTERFACE SCIENCE, cilt.534, ss.704-710, 2019 (SCI İndekslerine Giren Dergi) identifier identifier identifier

  • Cilt numarası: 534
  • Basım Tarihi: 2019
  • Doi Numarası: 10.1016/j.jcis.2018.09.075
  • Dergi Adı: JOURNAL OF COLLOID AND INTERFACE SCIENCE
  • Sayfa Sayıları: ss.704-710

Özet

Ruthenium(0) nanoparticles were successfully prepared on the surface of ceria (Ru-0/CeO2) and used as catalysts on glassy carbon electrode (GCE) in oxygen evolution reaction (OER) from water electrolysis at room temperature. Ru-0/CeO2 on GCE exhibits high catalytic activity for OER in alkaline solution. It provides a low onset potential of 1.57 V vs. RHE and low overpotential of 420 mV vs. RHE to reach a current density of 10 mA cm(-2). Ru-0/CeO2 on GCE shows no change in the onset potential value even after 6.1 h electrochemical measurement in OER. (C) 2018 Elsevier Inc. All rights reserved.