Manganese(III) acetate-mediated oxidative coupling of phenylhydrazines with benzene: a novel method for biaryl coupling


Demir A. , Reis O., Ozgul-Karaaslan E.

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, ss.3042-3045, 2001 (SCI İndekslerine Giren Dergi) identifier identifier

  • Basım Tarihi: 2001
  • Doi Numarası: 10.1039/b105119a
  • Dergi Adı: JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
  • Sayfa Sayıları: ss.3042-3045

Özet

The reaction of phenylhydrazines with benzene in the presence of manganese(III) acetate affords biaryls in good yields. The same reaction was carried out with similar oxidants, such as Co-III, Ce-IV and Pb-IV; among these oxidants Mn-III acetate shows higher efficiency and selectivity.