Manganese(III) acetate-mediated oxidative coupling of phenylhydrazines with benzene: a novel method for biaryl coupling

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Atıf İçin Kopyala

Demir A., Reis O., Ozgul-Karaaslan E.

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, sa.22, ss.3042-3045, 2001 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Basım Tarihi: 2001
• Doi Numarası: 10.1039/b105119a
• Dergi Adı: JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Sayfa Sayıları: ss.3042-3045
• Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

The reaction of phenylhydrazines with benzene in the presence of manganese(III) acetate affords biaryls in good yields. The same reaction was carried out with similar oxidants, such as Co-III, Ce-IV and Pb-IV; among these oxidants Mn-III acetate shows higher efficiency and selectivity.