Poly(o-anisidine) on brass: Synthesis and corrosion behavior


ÖZYILMAZ A. T. , ÖZYILMAZ G., Yilmaz E., Colak N.

KOREAN JOURNAL OF CHEMICAL ENGINEERING, cilt.25, ss.846-853, 2008 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 25 Konu: 4
  • Basım Tarihi: 2008
  • Doi Numarası: 10.1007/s11814-008-0140-0
  • Dergi Adı: KOREAN JOURNAL OF CHEMICAL ENGINEERING
  • Sayfa Sayıları: ss.846-853

Özet

The electrochemical synthesis of poly(o-anisidine) (POA) was achieved on brass (CuZn) electrode by applying two scan rates (50 and 20 mVs(-1)). The synthesized polymer films were strongly adherent and homogeneous in both cases. Their corrosion performance was investigated by AC impedance spectroscopy (EIS) technique, anodic polarization plots and open circuit potential-time curves, in 3.5% NaCl solution. It was clearly seen that poly(o-anisidine) films provided a significant physical protection for longer exposure time. It was shown that polymer film coated at high scan rate (CuZn/POA-H) exhibited better barrier property against the attack of corrosive agents when compared with polymer film obtained at low scan rate (CuZn/POA-L). It was found out that poly(o-anisidine) film synthesized at high scan rate caused a significant increase in corrosion resistance by its catalytic behavior on formation of protective oxide layers on the surface in longer time.