Conducting polymer composites of polypyrrole and polyindene


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Bozkurt A., Akbulut U. , Toppare L.

SYNTHETIC METALS, cilt.82, ss.41-46, 1996 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 82 Konu: 1
  • Basım Tarihi: 1996
  • Doi Numarası: 10.1016/s0379-6779(97)80007-0
  • Dergi Adı: SYNTHETIC METALS
  • Sayfa Sayıları: ss.41-46

Özet

Polypyrrole-polyindene composites were prepared via electrochemical methods. Two different approaches were utilized. In the first, the electro-initiated polymerization of indene on a platinum electrode was achieved at 2.0 V versus Ag/Ag+ in acetonitrile. Then the polyindene-coated electrode was used for the electrochemical polymerization of pyrrole at 1.0 V versus Ag/Ag+. In the second case, electrochemical coating of platinum electrode with polypyrrole at 1.0 V versus Ag/Ag+ was carried out and indene was polymerized on the conducting polymer at 2.0 V versus Ag/Ag+ in acetonitrile medium. The characterizations of these composites were done by FT-IR, scanning electron microscopy (SEM) and thermal gravimetric analysis (TGA). Electrical conductivities were evaluated by two-probe and four-probe methods.