THE ALPHA'-OXIDATION OF ALPHA-ALKOXY ENONES USING MANGANESE(III) ACETATE IN COMBINATION WITH CARBOXYLIC-ACIDS


DEMIR A. , SAATCIOGLU A.

SYNTHETIC COMMUNICATIONS, vol.23, no.5, pp.571-575, 1993 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 23 Issue: 5
  • Publication Date: 1993
  • Doi Number: 10.1080/00397919308009814
  • Title of Journal : SYNTHETIC COMMUNICATIONS
  • Page Numbers: pp.571-575

Abstract

The alpha'-oxidation of cyclic derivatives of alpha-alkoxy-alpha,beta-unsaturated ketones using manganese(III)acetate in the presence of various carboxylic acids provided a convenient synthesis of 5-acyloxy-2-alkoxy-2-cyclopentenones and 6-acyloxy-2-alkoxy-2-cyclohexenones.