Oxidation of Primary Alcohols to Aldehydes with N-Halamine-Containing Polymers


AKDAĞ A. , ÖZTÜRK P.

SYNLETT, vol.24, no.18, pp.2451-2453, 2013 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 24 Issue: 18
  • Publication Date: 2013
  • Doi Number: 10.1055/s-0033-1339840
  • Title of Journal : SYNLETT
  • Page Numbers: pp.2451-2453
  • Keywords: alcohols, aldehydes, oxidation, solid-phase synthesis, halogens, green chemistry, POLY(STYRENEHYDANTOIN) BEADS, SELECTIVE OXIDATION, TEMPO, CATALYSTS, HYPOCHLORITE, EFFICIENT, WATER

Abstract

Polymeric N-halamines have been previously employed for organic reactions such as sulfide oxidation. In the present study, we employed polymeric N-halamines to oxidize primary alcohols selectively to the corresponding aldehydes in excellent yields. After reaction, the polymers can be recycled and then reused for the next reaction process.