A new and efficient synthesis of indenone


Zengin M., Dastan A., Balci M.

SYNTHETIC COMMUNICATIONS, cilt.31, ss.1993-1999, 2001 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 31 Konu: 13
  • Basım Tarihi: 2001
  • Doi Numarası: 10.1081/scc-100104416
  • Dergi Adı: SYNTHETIC COMMUNICATIONS
  • Sayfa Sayıları: ss.1993-1999

Özet

Reaction of dichloroketone 2 with NEt3 gave indenone (4) in high yield. Catodic reaction of 2 in the presence of C/Pt electrodes afforded the rearranged product 3 in high yield besides a small amount of chlorohydroxyketone 5. Reaction of rearranged dichloroketone 3 with NEt3 provided indenone (4) as the sole product. The mechanism of these reaction was discussed.