Self-Assembled Containers Based on Extended Tetrathiafulvalene
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, cilt.135, sa.27, ss.10018-10021, 2013 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 135 Sayı: 27
- Basım Tarihi: 2013
- Doi Numarası: 10.1021/ja404072w
- Dergi Adı: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Index Chemicus (IC)
- Sayfa Sayıları: ss.10018-10021
- Orta Doğu Teknik Üniversitesi Adresli: Hayır
Özet
Two original self-assembled containers constituted each by six electroactive subunits are described. They are synthesized from a concave tetratopic pi-extended tetrathiafulvalene ligand bearing four pyridyl units and cis-M(dppf)(OTf)(2) (M = Pd or Pt; dppf = 1,1'-bis(diphenylphosphino)ferrocene; OTf = trifluoromethane-sulfonate) complexes. Both fully characterized assemblies present an oblate spheroidal cavity that can incorporate one perylene molecule.