Synthetic Lubricants Derived from Plastic Waste and their Tribological Performance


Hackler R. A., Vyavhare K., Kennedy R. M., ÇELİK G., Kanbur U., Griffin P. J., ...Daha Fazla

ChemSusChem, cilt.14, sa.19, ss.4181-4189, 2021 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 14 Sayı: 19
  • Basım Tarihi: 2021
  • Doi Numarası: 10.1002/cssc.202100912
  • Dergi Adı: ChemSusChem
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Applied Science & Technology Source, Chemical Abstracts Core, Chimica, Compendex, EMBASE, INSPEC, MEDLINE
  • Sayfa Sayıları: ss.4181-4189
  • Anahtar Kelimeler: depolymerization, lubricants, plastics, polyolefins, upcycling, CHAIN-LENGTH, POLYETHYLENE, PYROLYSIS, VISCOSITY, OIL, HYDROGENOLYSIS, EXTRACTION, PRESSURE, SURFACES, FUELS
  • Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

© 2021 Wiley-VCH GmbHThe energy efficiency, mechanical durability, and environmental compatibility of all moving machine components rely heavily on advanced lubricants for smooth and safe operation. Herein an alternative family of high-quality liquid (HQL) lubricants was derived by the catalytic conversion of pre- and post-consumer polyolefin waste. The plastic-derived lubricants performed comparably to synthetic base oils such as polyalphaolefins (PAOs), both with a wear scar volume (WSV) of 7.5×10−5 mm−3. HQLs also performed superior to petroleum-based lubricants such as Group III mineral oil with a WSV of 1.7×10−4 mm−3, showcasing a 44 % reduction in wear. Furthermore, a synergistic reduction in friction and wear was observed when combining the upcycled plastic lubricant with synthetic oils. Life cycle and techno-economic analyses also showed this process to be energetically efficient and economically feasible. This novel technology offers a cost-effective opportunity to reduce the harmful environmental impact of plastic waste on our planet and to save energy through reduction of friction and wear-related degradations in transportation applications akin to synthetic oils.