Ordering of water in opals with different microstructures


Eckert J., Gourdon O., Jacob D. E. , MERAL Ç. , Monteiro P. J. , Vogel S. C. , ...Daha Fazla

EUROPEAN JOURNAL OF MINERALOGY, cilt.27, sa.2, ss.203-213, 2015 (SCI İndekslerine Giren Dergi) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 27 Konu: 2
  • Basım Tarihi: 2015
  • Doi Numarası: 10.1127/ejm/2015/0027-2428
  • Dergi Adı: EUROPEAN JOURNAL OF MINERALOGY
  • Sayfa Sayıları: ss.203-213

Özet

Opal has long fascinated scientists. It is one of the few minerals with an amorphous structure, and yet, compared to silica glass, it is highly organized on the mesoscale. By means of inelastic neutron scattering (INS), we could document that in four samples of opal at low temperature an ice-like structure of water is present, with details depending on microstructural characteristics. While FTIR spectra for all samples are nearly identical and thus not very informative, INS shows clear differences, highlighting the significance of microstructures. Neutron diffraction at 100 K on one of the opal samples provides evidence for crystalline cubic ice.