ANODIC POTENTIAL HOMO ENERGY RELATIONS OF FLUORENE DERIVATIVES

SEN S., CELEBI N., TURKER L., ONAL A.

BULLETIN DES SOCIETES CHIMIQUES BELGES, vol.102, no.9, pp.583-587, 1993 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 102 Issue: 9
  • Publication Date: 1993
  • Doi Number: 10.1002/bscb.19931020904
  • Journal Name: BULLETIN DES SOCIETES CHIMIQUES BELGES
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.583-587
  • Middle East Technical University Affiliated: Yes

Abstract

Anodic oxidation peak potentials (E(p,a)) of some fluorene derivatives were measured on a Pt-degrees electrode versus Ag-degrees/Ag+ in acetonitrile-TBAFB by cyclic voltammetry. The highest occupied molecular orbital (HOMO) energies of the compounds were calculated within the Huckel molecular orbital (HMO) framework. The measured E(p,a) values were correlated to theoretical HOMO energies with a linear regression model.