Accurate lower and upper bounds of the energy spectrum for the asymmetrical two-well potentials


International Journal of Quantum Chemistry, vol.60, no.2, pp.641-648, 1996 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 60 Issue: 2
  • Publication Date: 1996
  • Title of Journal : International Journal of Quantum Chemistry
  • Page Numbers: pp.641-648


Trigonometric basis sets are used in a Rayleigh-Ritz variational method for computing two-sided eigenvalue bounds of the Schrödinger equation in one dimension. The method is based on truncating the infinite interval and solving an eigenvalue problem which obeys the von Neumann and the Dirichlet boundary conditions, respectively. Highly accurate numerical results are presented for the asymmetrical two-well oscillators. © 1996 John Wiley & Sons, Inc.