Template-Directed Photochemical Homodimerization and Heterodimerization Reactions of Cinnamic Acids
JOURNAL OF ORGANIC CHEMISTRY, cilt.86, sa.18, ss.13118-13128, 2021 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 86 Sayı: 18
- Basım Tarihi: 2021
- Doi Numarası: 10.1021/acs.joc.1c01534
- Dergi Adı: JOURNAL OF ORGANIC CHEMISTRY
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, BIOSIS, Chemical Abstracts Core, Chimica, Compendex, EMBASE, MEDLINE, Index Chemicus (IC)
- Sayfa Sayıları: ss.13118-13128
- Orta Doğu Teknik Üniversitesi Adresli: Hayır
Özet
We developed a general method for the selective photochemical homo- and heterodimerization of cinnamic acid derivatives with the use of commercially available 1,8-dihydroxynaphthalene as a covalent template. A variety of symmetrical and unsymmetrical beta-truxinic acids were obtained in high yields and as single diastereomers. The use of a template not only provides the alignment of the two olefins with suitable proximity (<4.2 angstrom) but also allows the heterodimerization of two different cinnamic acids, leading to unsymmetrical beta-truxinic acid products.