Zinc Chalcogenide Based Shell Layers for Colloidal Quantum Wells
Advanced Materials Interfaces, cilt.12, sa.12, 2025 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 12 Sayı: 12
- Basım Tarihi: 2025
- Doi Numarası: 10.1002/admi.202500120
- Dergi Adı: Advanced Materials Interfaces
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Applied Science & Technology Source, Compendex, INSPEC
- Anahtar Kelimeler: colloidal nanoplatelets, colloidal quantum wells, colloidal semiconductor nanocrystals, core shell heterostructures, light-emitting devices
- Orta Doğu Teknik Üniversitesi Adresli: Evet
Özet
Colloidal quantum wells, also known as colloidal nanoplatelets (NPLs), have emerged as a promising class of materials for light-emitting devices (LEDs). However, the most widely studied core/shell NPLs, which rely on cadmium-based shell layers, face challenges due to toxicity concerns and improper charge confinement. To address these limitations, a new synthetic approach is presented that enables the controlled growth of zinc chalcogenide-based shell layers on NPLs. The synthesized CdSe/ZnSe core/shell NPLs exhibit emission between 615 and 630 nm, with a moderate photoluminescence quantum yield (PL-QY) of 40–50%. It is also demonstrated that the lateral dimensions of the CdSe core NPLs significantly affect the optical properties of the core/shell heterostructures, with smaller lateral dimensions resulting in narrower emission linewidths as low as 20 nm. Further passivation of these core/shell NPLs with an additional ZnS shell layer significantly increases the PL-QY up to 80–90%. Finally, the device performance of these two core/shell NPLs is investigated by fabricating solution-processed LEDs. With LEDs incorporating CdSe/ZnSe/ZnS core/multi-shell NPLs as the active light-emitting layer, an external quantum efficiency (EQE) of 3.82% and a maximum brightness of 6477 cd m−2 is obtained. These findings underscore the significant potential of zinc chalcogenide-based shell layers in advancing colloidal NPLs toward high-performance light-emitting devices.