1SR,2SR,3SR,4RS,5RS,6RS,7SR,8RS)-7,8-dichlorobicyclo[4.2.0]octa-2,3,4,5-tetrayl tetraacetate


Sahin E., Kelebekli L., Kara Y., Balci M.

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, vol.62, 2006 (Journal Indexed in SCI) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 62
  • Publication Date: 2006
  • Doi Number: 10.1107/s0108270106018336
  • Title of Journal : ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS

Abstract

In the title compound, C16H20Cl2O8, the bicyclic system contains a central non-planar cyclohexane ring which is fused to a cyclobutane moiety. The cyclohexane ring has a chair conformation and the whole system adopts a syn conformation. The structure provides information on the stereochemical course of the chlorination, photo-oxidation and hydroxylation steps of the reaction.