Photovoltaic and photophysical properties of a novel bis-3-hexylthiophelle substituted quinoxaline derivative

GÜNEŞ S., Baran D., Guenbas G., Oezyurt F., Fuchsbauer A., Sariciftci N. S., ...Daha Fazla

SOLAR ENERGY MATERIALS AND SOLAR CELLS, cilt.92, sa.9, ss.1162-1169, 2008 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 92 Sayı: 9
  • Basım Tarihi: 2008
  • Doi Numarası: 10.1016/j.solmat.2008.04.004
  • Dergi Adı: SOLAR ENERGY MATERIALS AND SOLAR CELLS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1162-1169
  • Anahtar Kelimeler: organic solar cells, conjugated polymers, electrochromic polymers, bulk heterojunction solar cells, novel thiophene derivative, POLYMER SOLAR-CELLS, BAND-GAP POLYMER, LARGE-AREA, MORPHOLOGY, BENZOTHIADIAZOLE, PERFORMANCE, THIOPHENE, ELECTRON, DEVICES
  • Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

We report on the photophysical properties and photovoltaic performance of a polythiophene derivative, poly-2,3-bis(4-tert-butylphenyl)-5,8-bis(4-hexylthiophen-2-yl)quinoxaline(PHTQ) as an electron donor in bulk heterojunction Solar Cells blended with the acceptor 1-(3-met hoxycarbonyl)propyl-1-phenyl-[6,6]-methanofullerence (PCBM). Devices were composed of PHTQ and varying amounts of PCBM (1:1, 1:2, 1:3, 1:4 w-w ratio). The components were spin cast from ortho-dichlorobenzene (ODCB) and characterized by measuring current-voltage characteristics under simulated AM 1.5 conditions. Efficiencies up to 0.3% have been reached. Incident photon to current efficiency (IPCE) is reported and the nanoscale morphology was investigated with atomic force microscopy (AFM). Photoinduced absorption spectroscopy confirms the photoinduced charge transfer in such donor acceptor blends. (c) 2008 Elsevier B.V. All rights reserved.