A facile synthesis of (+/-)-mintlactone

Tanyeli C., ÇALİŞKAN Z., Demir A.

SYNTHETIC COMMUNICATIONS, cilt.27, sa.19, ss.3471-3476, 1997 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 27 Sayı: 19
  • Basım Tarihi: 1997
  • Doi Numarası: 10.1080/00397919708005649
  • Dergi Adı: SYNTHETIC COMMUNICATIONS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.3471-3476
  • Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

(+/-)-Mintlactone has been synthesized by applying a novel effective synthetic sequence. 4-Methylcyclohexanone was subjected to acetoxylation with Pb(OAc)(4). Hydrolysis followed by reaction with 2-chloroprogionyl chloride,then treatment with triethyl phosphite and, finally, Horner-Emmons-type intramolecular cyclization afforded (+/-)-Mintlactone.