The synthesis and characterization of new metal-free and metallo phthalocyanines substituted with four dithiatetraoxa macrocyclic moieties


Kantekin H., Rakap M., Misir M. N., Goek H. Z., Acar I.

JOURNAL OF COORDINATION CHEMISTRY, cilt.60, sa.18, ss.1965-1972, 2007 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 60 Sayı: 18
  • Basım Tarihi: 2007
  • Doi Numarası: 10.1080/00958970701217412
  • Dergi Adı: JOURNAL OF COORDINATION CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1965-1972
  • Orta Doğu Teknik Üniversitesi Adresli: Hayır

Özet

New metal-free phthalocyanine ( 7) fused symmetrically in peripheral positions with four dithiatetraoxa macrocycles, has been synthesized by cyclotetramerization of the isoindoline-diimine derivative of macrocyclic 6. Metallophthalocyanine ( 8) was synthesized by reaction of phthalonitrile derivative ( 5) with anhydrous nickel( II) chloride. The new compounds were characterized by elemental analysis, H-1 and C-13-NMR, IR UV-Vis and mass spectroscopies.