Propynylferrocene and (phenylethynyl)ferrocene

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Zora M., Acikgoz C., Tumay T. A., Odabasoglu M., Buyukgungor O.

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, cilt.62, 2006 (SCI-Expanded, Scopus)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 62
• Basım Tarihi: 2006
• Doi Numarası: 10.1107/s0108270106022438
• Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

The title compounds, propynylferrocene, [Fe(C5H5)(C8H7)], (I), and (phenylethynyl) ferrocene, [Fe(C5H5)(C13H9)], (II), are stabilized by weak C-H center dot center dot center dot pi interactions. The C C bond distances in these molecules are in the range 1.182 (3)-1.192 (3) angstrom. In (II), the ferrocenyl and phenyl groups are perpendicular, making an angle of 89.06 (13)degrees, which is a rare occurrence.