Autonomous Shuttling Driven by an Oscillating Reaction: Proof of Principle in a Cucurbit[7]uril-Bodipy Pseudorotaxane


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Buyukcakir O., Yasar F. T. , BOZDEMİR Ö. A. , Icli B., AKKAYA E. U.

ORGANIC LETTERS, cilt.15, ss.1012-1015, 2013 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 15 Konu: 5
  • Basım Tarihi: 2013
  • Doi Numarası: 10.1021/ol303495n
  • Dergi Adı: ORGANIC LETTERS
  • Sayfa Sayıları: ss.1012-1015

Özet

A bipyridinium dication-substituted Bodipy fluorophore, with a terminal carboxylic acid function, provides two alternative stations for cucurbit[7]uril. Changing pH from basic to acidic results in shuttling of the cucurbit[7]uril from one station to another. In addition, this shuttling is accompanied by a change in the emissive properties of the Bodipy dye, which is only observed in the presence of cucurbit[7]uril. More striking, is a demonstration of autonomous shuttling of the pseudorotaxane system in an oscillating pH system.