Asymmetric benzoin reaction catalyzed by benzoylformate decarboxylase
TETRAHEDRON-ASYMMETRY, cilt.10, sa.24, ss.4769-4774, 1999 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 10 Sayı: 24
- Basım Tarihi: 1999
- Doi Numarası: 10.1016/s0957-4166(99)00516-9
- Dergi Adı: TETRAHEDRON-ASYMMETRY
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.4769-4774
- Orta Doğu Teknik Üniversitesi Adresli: Evet
Özet
Aromatic aldehydes are converted into benzoins by benzoylformate decarboxylase catalyzed C-C bond formation. The reaction affords (R)-benzoins with high enantiomeric excess and in good chemical yields. A broad range of aromatic aldehydes can be used as substrates in aqueous buffer or buffer/DMSO-solutions. (C) 2000 Elsevier Science Ltd. All rights reserved.