Terahertz absorption spectrum of para and ortho water vapors at different humidities at room temperature


Xin X., Altan H., Saint A., Matten D., Alfano R. R.

JOURNAL OF APPLIED PHYSICS, vol.100, no.9, 2006 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 100 Issue: 9
  • Publication Date: 2006
  • Doi Number: 10.1063/1.2357412
  • Journal Name: JOURNAL OF APPLIED PHYSICS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Middle East Technical University Affiliated: Yes

Abstract

Terahertz time-domain spectroscopy has been used to measure the absorption of water vapor in 0.2-2.4 THz range from low to high humidity at room temperature. The observed absorption lines are due to the water molecular rotations in the ground vibrational state. We find that the absorption strength of para transitions increases as humidity increases, while the absorption strength of ortho transitions increases and then decreases in intensity with increasing humidity. We explain this difference based on the nuclear spin statistics based ratio of ortho to para water monomer populations at room temperature. The preferential adsorption on the solid surfaces of para water leads to an ortho dominated vapor cloud whose monomer rotational absorption intensity decreases due to the effects of dimerization, molecular collisions, clustering, and interactions with liquid droplets at high concentrations. (c) 2006 American Institute of Physics.