The effect of peripheral circuits on the total pi-electron energies of cyclacenes


Turker L.

TURKISH JOURNAL OF CHEMISTRY, cilt.24, ss.217-222, 2000 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 24 Konu: 3
  • Basım Tarihi: 2000
  • Dergi Adı: TURKISH JOURNAL OF CHEMISTRY
  • Sayfa Sayıları: ss.217-222

Özet

Within the framework of the Huckel molecular orbital theory, certain linear models are developed to express the contribution of peripheral circuits of cyclacenes into their total pi -electron energies, which explain why cyclacenes exhibit the cryptoannulenic behavior as their peripheral circuits which are annulenic in character.