Green synthesis of iron nanoparticles and their application as a Fenton-like catalyst for the degradation of aqueous cationic and anionic dyes

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Shahwan T., Abu Sirriah S., Nairat M., Boyaci E., Eroglu A. E., Scott T. B., ...More

CHEMICAL ENGINEERING JOURNAL, vol.172, no.1, pp.258-266, 2011 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 172 Issue: 1
  • Publication Date: 2011
  • Doi Number: 10.1016/j.cej.2011.05.103
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.258-266
  • Keywords: Green synthesis, Iron nanoparticles, Methylene blue, Methyl orange, Fenton catalyst, ADSORPTION BEHAVIOR, METHYLENE-BLUE, VALENT, XPS, REMOVAL, WATER, IONS
  • Middle East Technical University Affiliated: No


Iron nanoparticles were produced using extracts of green tea leaves (GT-Fe NPs). The materials were characterized using TEM. SEM/EDX, XPS, XRD, and FTIR techniques and were shown to contain mainly iron oxide and iron oxohydroxide. The obtained nanoparticles were then utilized as a Fenton-like catalyst for decolorization of aqueous solutions containing methylene blue (MB) and methyl orange (MO) dyes. The related experiments investigated the removal kinetics and the effect of concentration for both MB and MO. The concentrations of dyes in aqueous solution were monitored using ultraviolet-visible (UV-vis) spectroscopy. The results indicated fast removal of the dyes with the kinetic data of MB following a second order removal rate, while those of MO were closer to a first order removal rate. The loading experiments indicated almost complete removal of both dyes from water over a wide range of concentration, 10-200 mg L-1. Compared with iron nanoparticles produced by borohydride reduction, GT-Fe nanoparticles demonstrated more effective capability as a Fenton-like catalyst, both in terms of kinetics and percentage removal. (C) 2011 Elsevier B.V. All rights reserved.