X-ray powder diffraction and IR study of NaMg(H2O)(2)[BP2O8]center dot H2O and NH4Mg(H2O)(2)[BP2O8]center dot H2O

Baykal A., Kizilyalli M., Kniep R.

JOURNAL OF MATERIALS SCIENCE, cilt.35, sa.18, ss.4621-4626, 2000 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 35 Sayı: 18
  • Basım Tarihi: 2000
  • Doi Numarası: 10.1023/a:1004818132238
  • Dergi Adı: JOURNAL OF MATERIALS SCIENCE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.4621-4626
  • Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

NaMg(H2O)(2)[BP2O8]. H2O was prepared by hydrothermal synthesis and was characterized by X-ray powder difraction and IR method. The title compound was synthesized from MgCl2. 6H(2)O, NaBO3. 4H(2)O, and (NH4)(2)HPO4 with variable molar ratios using hydrothermal method by heating at 165 degrees C for 3 days. The X-ray powder diffraction data was indexed in hexagonal system, the unit cell parameters were found to be as a = 9.428, c = 15.82 Angstrom, Z = 4 and the space group is P6(1)22. It is isostructural with (MMII)-M-I(H2O)[BP2O8] type compounds where M-I = Na, K; M-II = Mg, Mn, Fe, Co, Ni and Zn. In addition NH4Mg(H2O)(2)[BP2O8]. H2O was also synthesized the first time in this research. Its unit cell parameters and hkl values were in good agreement with the sodium magnesium compound. The unit cell parameters are a = 9.529, c = 15.736 Angstrom. The indexed X-ray powder diffraction data of both compounds which were not reported in the literature is presented in this work. The IR data of NaMg(H2O)(2)[BP2O8]. H2O is also reported. (C) 2000 Kluwer Academic Publishers.