An investigation of the formation mechanism of allene or alkyne in the 6,7-benzobicyclo[3,2.1]octane system by deuterium labeling experiments


Taskesenligil Y., Tumer F., Kazaz C., Balci M.

TURKISH JOURNAL OF CHEMISTRY, cilt.23, ss.115-122, 1999 (SCI İndekslerine Giren Dergi) identifier

  • Cilt numarası: 23 Konu: 2
  • Basım Tarihi: 1999
  • Dergi Adı: TURKISH JOURNAL OF CHEMISTRY
  • Sayfa Sayıları: ss.115-122

Özet

In order to reveal the real intermediate in the base-promoted reaction of 1, 3-bromo-4,4-dideuterio-6,7-benaobicyclo[3.2.1]octa-2,6-diene 10 was synthesized and its HBr elimination reaction studied. Reaction of 10 with potassium tert-butoxide yielded butoxyl ether 18 in which proton-deuterium exchange has occured.