An investigation of the formation mechanism of allene or alkyne in the 6,7-benzobicyclo[3,2.1]octane system by deuterium labeling experiments

Taskesenligil Y., Tumer F., Kazaz C., Balci M.

TURKISH JOURNAL OF CHEMISTRY, vol.23, no.2, pp.115-122, 1999 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 23 Issue: 2
  • Publication Date: 1999
  • Journal Name: TURKISH JOURNAL OF CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, TR DİZİN (ULAKBİM)
  • Page Numbers: pp.115-122
  • Middle East Technical University Affiliated: No

Abstract

In order to reveal the real intermediate in the base-promoted reaction of 1, 3-bromo-4,4-dideuterio-6,7-benaobicyclo[3.2.1]octa-2,6-diene 10 was synthesized and its HBr elimination reaction studied. Reaction of 10 with potassium tert-butoxide yielded butoxyl ether 18 in which proton-deuterium exchange has occured.