Temperature and pressure dependence of the Raman frequency shifts near the melting point in ice I


Yurtseven H., Karacali H.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, cilt.64, sa.3, ss.771-777, 2006 (SCI-Expanded) identifier identifier identifier

Özet

This study examines the validity of the spectroscopic modification of the Pippard relations for the hexagonal ice (ice I) close to the melting point. A linear variation of the specific heat C-P with the frequency shifts 1/nu(partial derivative nu/partial derivative P)(p) is obtained for ice I. This linearity is also obtained between thermal expansivity alpha P and the frequency shifts (partial derivative nu/partial derivative P)(T) close to the melting point in this crystal. (c) 2005 Elsevier B.V. All rights reserved.