Synthesis and characterizations of 3,3 '-bis(diphenylphosphinoamine)-2,2 '-bipyridine and 3,3 '-bis(diphenylphosphinite)-2,2 '-bipyridine and their chalcogenides

Baysal A., Aydemir M., Durap F., Guemguem B., Oezkar S., Yildirim L. T.

POLYHEDRON, vol.26, no.13, pp.3373-3378, 2007 (Peer-Reviewed Journal) identifier identifier

  • Publication Type: Article / Article
  • Volume: 26 Issue: 13
  • Publication Date: 2007
  • Doi Number: 10.1016/j.poly.2007.03.027
  • Journal Name: POLYHEDRON
  • Journal Indexes: Science Citation Index Expanded, Scopus
  • Page Numbers: pp.3373-3378
  • Keywords: aminophosphine, phosphinite, diphenylchlorophosphine, X-ray diffraction, 3,3'-bis(diphenylthiophosphinite)-2,2'-bipyridine, NMR, COORDINATION CHEMISTRY, ASYMMETRIC HYDROGENATION, AMINOPHOSPHINE-PHOSPHINITES, LIGANDS, COMPLEXES, REACTIVITY, DERIVATIVES, AUXILIARIES, CRYSTAL


New bis(phosphinoamine) and bis(phosphinite) derivatives of 2,2'-bipyridine were prepared through a single step reaction of 3,3'-diamino-2,2'-bipyridine or 3,3'-dihydroxy-2,2'-bipyridine with diphenylehlorophosphine, respectively. Their P = E chalcogenides (E = 0, S, Se) were also prepared. All the new compounds were characterized by elemental analysis, IR and NMR spectroscopies. The molecular structure of 3.3'-bis(diphenylthiophosphinite)-2,2'-bipyridine was elucidated by single-crystal X-ray crystallography. (c) 2007 Elsevier Ltd. All rights reserved.