Intramolecular through-space charge transfer between benzofuran and ynone groups on a naphthalene spacer

Calikyilmaz E., Karaoglu G., Demir M., ŞAHİN O., Ulgut B., AKDAĞ A., ...Daha Fazla

CHEMICAL COMMUNICATIONS, cilt.60, sa.5, ss.550-553, 2024 (SCI-Expanded, Scopus) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 60 Sayı: 5
  • Basım Tarihi: 2024
  • Doi Numarası: 10.1039/d3cc05109a
  • Dergi Adı: CHEMICAL COMMUNICATIONS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core, Chimica, Communication Abstracts, Compendex, EMBASE, MEDLINE, DIALNET, Index Chemicus (IC), Nature Index
  • Sayfa Sayıları: ss.550-553
  • Orta Doğu Teknik Üniversitesi Adresli: Evet

Özet

We have developed a new scaffold that exhibits an efficient intramolecular through-space charge transfer (CT). In this design, electron-rich benzofuran and electron-deficient ynone groups are placed strategically in proximity via a naphthalene spacer. Charge transfer is supported by distinct CT bands in the visible region (>500 nm) in their UV-vis absorption and emission spectra.