Synthesis of conducting H-type polysiloxane-polypyrrole block copolymers

Kalaycioglu E., Toppare L. , Yagci Y., Harabagiu V., Pintela M., Ardelean R., ...Daha Fazla

SYNTHETIC METALS, cilt.97, sa.1, ss.7-12, 1998 (SCI İndekslerine Giren Dergi) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 97 Konu: 1
  • Basım Tarihi: 1998
  • Doi Numarası: 10.1016/s0379-6779(98)00097-6
  • Sayfa Sayıları: ss.7-12


Synthesis of a siloxane polymer with pyrrole end groups has been described. Electrochemical block polymerization of pyrrole through these end groups has been achieved. Characterization of the electrolytic products has been performed by means of scanning electron microscopy (SEM), differential scanning calorimetry (DSC), thermal gravimetry analysis (TGA) analyses and FT-IR studies. The effects of different dopant ions, namely, p-toluene sulfonic acid (PTSA) and tetrabutylammonium tetrafluoroborate (TBAFB), in electropolymerization and conductivities of the corresponding block copolymers have been investigated. (C) 1998 Elsevier Science S.A. All rights reserved.