Development of visible-light-active Fe2O3-hBN photocatalysts for sustainable degradation of emerging pollutants under simulated sunlight conditions
Journal of Hazardous Materials Advances, vol.21, 2026 (ESCI, Scopus)
- Publication Type: Article / Article
- Volume: 21
- Publication Date: 2026
- Doi Number: 10.1016/j.hazadv.2026.101064
- Journal Name: Journal of Hazardous Materials Advances
- Journal Indexes: Emerging Sources Citation Index (ESCI), Scopus, Chemical Abstracts Core, INSPEC, Directory of Open Access Journals
- Keywords: Environmental remediation, Fe2O3-hBN composites, Ibuprofen, Methylene blue, Photocatalysis, Sunlight irradiation, Water treatment
- Middle East Technical University Affiliated: Yes
Abstract
In this work, Fe2O3-hBN composites with different Fe2O3 loadings (0.2–2 wt%) were synthesized via a dry impregnation approach and evaluated as sustainable photocatalysts for water purification. The materials were comprehensively characterized using XRD, SEM, TEM, XPS, FTIR, UV–Vis, PL, and N2 adsorption-desorption analyses to elucidate their structural, optical, and surface properties. Under simulated solar irradiation, the 0.5 wt% Fe2O3-hBN composite showed the most efficient photocatalytic activity among the tested materials. Approximately 80% removal of methylene blue and more than 70% degradation of ibuprofen were achieved within 120 min, highlighting the superior performance of this composition. This improvement was attributed to enhanced visible-light absorption and a reduced band gap (2.7 eV). Radical scavenging experiments identified photogenerated holes (h*) and superoxide radicals (O3*-) as the main reactive species. The composite exhibited excellent stability and reusability across multiple cycles. These findings highlight Fe2O3-hBN as an efficient and eco-friendly photocatalyst for sustainable water remediation applications.