© 2021 authors. Published by the American Physical Society. Published by the American Physical Society under the terms of the "https://creativecommons.org/licenses/by/4.0/"Creative Commons Attribution 4.0 International license. Further distribution of this work must maintain attribution to the author(s) and the published article's title, journal citation, and DOI. Funded by SCOAP3.In this paper, we analyze the vertices of doubly heavy spin-3/2-spin-1/2 baryons with light mesons within the method of light-cone QCD sum rules. These vertices are parametrized in terms of one (three) coupling constant(s) for the pseudoscalar (vector) mesons. The said coupling constants are calculated for all possible transitions. The results presented here can serve as useful information in experimental as well as theoretical studies of the properties of doubly heavy baryons.